Yes, as long as you have shared custody and your child’s expenses are included in your tax return (your tax return will not show the child’s NIF).
If you are paying alimony without shared custody, you can also use Edenred Creche to pay part of the alimony, as this is also used for education expenses.
If you don’t have shared custody or pay child support, you can’t use Edenred Creche.